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4-Anilino-3-nitro­benzonitrile

In the title compound, C(13)H(9)N(3)O(2), the aromatic rings are twisted with respect to each other, making a dihedral angle of 49.41 (9)°. The nitro group and the nitrile group are nearly in the plane of the benzonitrile ring, the largest deviation from the plane being 0.123 (1) Å. There is an intr...

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Detalles Bibliográficos
Autores principales: Wang, Yong, Fan, Kaiqing, Li, Chenghong, Ge, Changhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011760/
https://www.ncbi.nlm.nih.gov/pubmed/21589567
http://dx.doi.org/10.1107/S1600536810043862
Descripción
Sumario:In the title compound, C(13)H(9)N(3)O(2), the aromatic rings are twisted with respect to each other, making a dihedral angle of 49.41 (9)°. The nitro group and the nitrile group are nearly in the plane of the benzonitrile ring, the largest deviation from the plane being 0.123 (1) Å. There is an intra­molecular N—H⋯O hydrogen bond forming an S(6) ring. Weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into a chain parallel to the c axis. Futhermore, slipped π–π inter­actions between symmetry-related phenyl rings [centroid–centroid distance 3.808 (1) Å, inter­planar distance 3.544 (8) Å with an offset of 21.5°] stabilize the structure.