Ni(2)Sr(PO(4))(2)·2H(2)O

The title compound, dinickel(II) strontium bis­[ortho­phosphate(V)] dihydrate, was obtained under hydro­thermal conditions. The crystal structure consists of linear chains (∞) (1)[NiO(2/2)(OH(2))(2/2)O(2/1)] of edge-sharing NiO(6) octa­hedra ([Image: see text] symmetry) running parallel to [010]. Ad...

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Detalles Bibliográficos
Autores principales: Assani, Abderrazzak, Saadi, Mohamed, Zriouil, Mohammed, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011770/
https://www.ncbi.nlm.nih.gov/pubmed/21589209
http://dx.doi.org/10.1107/S1600536810045113
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author Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_facet Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_sort Assani, Abderrazzak
collection PubMed
description The title compound, dinickel(II) strontium bis­[ortho­phosphate(V)] dihydrate, was obtained under hydro­thermal conditions. The crystal structure consists of linear chains (∞) (1)[NiO(2/2)(OH(2))(2/2)O(2/1)] of edge-sharing NiO(6) octa­hedra ([Image: see text] symmetry) running parallel to [010]. Adjacent chains are linked to each other through PO(4) tetra­hedra (m symmetry) and arranged in such a way to build layers parallel to (001). The three-dimensional framework is accomplished by stacking of adjacent layers that are held together by SrO(8) polyhedra (2/m symmetry). Two types of O—H⋯O hydrogen bonds involving the water mol­ecule are present, viz. one very strong hydrogen bond perpendicular to the layers and weak trifurcated hydrogen bonds parallel to the layers.
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spelling pubmed-30117702010-12-30 Ni(2)Sr(PO(4))(2)·2H(2)O Assani, Abderrazzak Saadi, Mohamed Zriouil, Mohammed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, dinickel(II) strontium bis­[ortho­phosphate(V)] dihydrate, was obtained under hydro­thermal conditions. The crystal structure consists of linear chains (∞) (1)[NiO(2/2)(OH(2))(2/2)O(2/1)] of edge-sharing NiO(6) octa­hedra ([Image: see text] symmetry) running parallel to [010]. Adjacent chains are linked to each other through PO(4) tetra­hedra (m symmetry) and arranged in such a way to build layers parallel to (001). The three-dimensional framework is accomplished by stacking of adjacent layers that are held together by SrO(8) polyhedra (2/m symmetry). Two types of O—H⋯O hydrogen bonds involving the water mol­ecule are present, viz. one very strong hydrogen bond perpendicular to the layers and weak trifurcated hydrogen bonds parallel to the layers. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011770/ /pubmed/21589209 http://dx.doi.org/10.1107/S1600536810045113 Text en © Assani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
Ni(2)Sr(PO(4))(2)·2H(2)O
title Ni(2)Sr(PO(4))(2)·2H(2)O
title_full Ni(2)Sr(PO(4))(2)·2H(2)O
title_fullStr Ni(2)Sr(PO(4))(2)·2H(2)O
title_full_unstemmed Ni(2)Sr(PO(4))(2)·2H(2)O
title_short Ni(2)Sr(PO(4))(2)·2H(2)O
title_sort ni(2)sr(po(4))(2)·2h(2)o
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011770/
https://www.ncbi.nlm.nih.gov/pubmed/21589209
http://dx.doi.org/10.1107/S1600536810045113
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