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Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)]
In the title centrosymmetric dinuclear complex, [Eu(2)(CH(3)CO(2))(6)(C(12)H(8)N(2))(2)], the Eu(III) atom is nine-coordinated by two N atoms from a 1,10-phenanthroline ligand and seven O atoms from five acetate ligands (two bidentate, three monodentate). The crystal structure is stabilized by π–π s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011772/ https://www.ncbi.nlm.nih.gov/pubmed/21589254 http://dx.doi.org/10.1107/S1600536810046131 |
| _version_ | 1782195023663595520 |
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| author | Fan, Rui-Qing Sun, Cun-Fa Yang, Yu-Lin |
| author_facet | Fan, Rui-Qing Sun, Cun-Fa Yang, Yu-Lin |
| author_sort | Fan, Rui-Qing |
| collection | PubMed |
| description | In the title centrosymmetric dinuclear complex, [Eu(2)(CH(3)CO(2))(6)(C(12)H(8)N(2))(2)], the Eu(III) atom is nine-coordinated by two N atoms from a 1,10-phenanthroline ligand and seven O atoms from five acetate ligands (two bidentate, three monodentate). The crystal structure is stabilized by π–π stacking interactions between the pyridine and benzene rings of adjacent molecules, with a centroid–centroid distance of 3.829 (2) Å. |
| format | Text |
| id | pubmed-3011772 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30117722010-12-30 Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)] Fan, Rui-Qing Sun, Cun-Fa Yang, Yu-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear complex, [Eu(2)(CH(3)CO(2))(6)(C(12)H(8)N(2))(2)], the Eu(III) atom is nine-coordinated by two N atoms from a 1,10-phenanthroline ligand and seven O atoms from five acetate ligands (two bidentate, three monodentate). The crystal structure is stabilized by π–π stacking interactions between the pyridine and benzene rings of adjacent molecules, with a centroid–centroid distance of 3.829 (2) Å. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011772/ /pubmed/21589254 http://dx.doi.org/10.1107/S1600536810046131 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fan, Rui-Qing Sun, Cun-Fa Yang, Yu-Lin Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)] |
| title | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_full | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_fullStr | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_full_unstemmed | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_short | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_sort | tetra-μ-acetato-κ(4)
o:o′;κ(3)
o,o′:o;κ(3)
o:o,o′-bis[(acetato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)europium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011772/ https://www.ncbi.nlm.nih.gov/pubmed/21589254 http://dx.doi.org/10.1107/S1600536810046131 |
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