Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate

The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro­thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra­zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid­yl)tetra­zolide liga...

Descripción completa

Detalles Bibliográficos
Autores principales: Mu, Yi-Qiang, Zhao, Jun, Li, Cai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011773/
https://www.ncbi.nlm.nih.gov/pubmed/21589327
http://dx.doi.org/10.1107/S1600536810048464
_version_ 1782195023897427968
author Mu, Yi-Qiang
Zhao, Jun
Li, Cai
author_facet Mu, Yi-Qiang
Zhao, Jun
Li, Cai
author_sort Mu, Yi-Qiang
collection PubMed
description The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro­thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra­zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid­yl)tetra­zolide ligands and four coordinated water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the pyridine and tetra­zole rings is 9.920 (7)°. In the crystal, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds involving the tetra­zole group N atoms, the aqua ligands and solvent water mol­ecules.
format Text
id pubmed-3011773
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30117732010-12-30 Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate Mu, Yi-Qiang Zhao, Jun Li, Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro­thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra­zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid­yl)tetra­zolide ligands and four coordinated water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the pyridine and tetra­zole rings is 9.920 (7)°. In the crystal, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds involving the tetra­zole group N atoms, the aqua ligands and solvent water mol­ecules. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011773/ /pubmed/21589327 http://dx.doi.org/10.1107/S1600536810048464 Text en © Mu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mu, Yi-Qiang
Zhao, Jun
Li, Cai
Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title_full Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title_fullStr Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title_full_unstemmed Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title_short Tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κN (5)]zinc(II) tetra­hydrate
title_sort tetra­aqua­bis­[5-(3-pyrid­yl)tetra­zolido-κn (5)]zinc(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011773/
https://www.ncbi.nlm.nih.gov/pubmed/21589327
http://dx.doi.org/10.1107/S1600536810048464
work_keys_str_mv AT muyiqiang tetraaquabis53pyridyltetrazolidokn5zinciitetrahydrate
AT zhaojun tetraaquabis53pyridyltetrazolidokn5zinciitetrahydrate
AT licai tetraaquabis53pyridyltetrazolidokn5zinciitetrahydrate

Ejemplares similares