Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-tri­yltris­(aza­nedi­yl)]triacetate

The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydro­chloride in reflux (dried toluene) under anhydrous atmosphere. Individual mol­ecules self-assemble via strong N—H⋯O hydrogen bonds into sup...

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Detalles Bibliográficos
Autores principales: Vilela, Sérgio M. F., Almeida Paz, Filipe A., Tomé, João P. C., de Zea Bermudez, Verónica, Cavaleiro, José A. S., Rocha, João
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011776/
https://www.ncbi.nlm.nih.gov/pubmed/21589531
http://dx.doi.org/10.1107/S1600536810047604
Descripción
Sumario:The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydro­chloride in reflux (dried toluene) under anhydrous atmosphere. Individual mol­ecules self-assemble via strong N—H⋯O hydrogen bonds into supra­molecular double tapes running parallel to the [010] crystallographic direction. The close packing of supra­molecular tapes is mediated by geometrical reasons in tandem with a number of weaker N—H⋯O and C—H⋯N hydrogen-bonding inter­actions.

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