Cargando…
Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate
The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N—H⋯O hydrogen bonds into sup...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011776/ https://www.ncbi.nlm.nih.gov/pubmed/21589531 http://dx.doi.org/10.1107/S1600536810047604 |
| _version_ | 1782195024592633856 |
|---|---|
| author | Vilela, Sérgio M. F. Almeida Paz, Filipe A. Tomé, João P. C. de Zea Bermudez, Verónica Cavaleiro, José A. S. Rocha, João |
| author_facet | Vilela, Sérgio M. F. Almeida Paz, Filipe A. Tomé, João P. C. de Zea Bermudez, Verónica Cavaleiro, José A. S. Rocha, João |
| author_sort | Vilela, Sérgio M. F. |
| collection | PubMed |
| description | The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N—H⋯O hydrogen bonds into supramolecular double tapes running parallel to the [010] crystallographic direction. The close packing of supramolecular tapes is mediated by geometrical reasons in tandem with a number of weaker N—H⋯O and C—H⋯N hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-3011776 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30117762010-12-30 Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate Vilela, Sérgio M. F. Almeida Paz, Filipe A. Tomé, João P. C. de Zea Bermudez, Verónica Cavaleiro, José A. S. Rocha, João Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N—H⋯O hydrogen bonds into supramolecular double tapes running parallel to the [010] crystallographic direction. The close packing of supramolecular tapes is mediated by geometrical reasons in tandem with a number of weaker N—H⋯O and C—H⋯N hydrogen-bonding interactions. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011776/ /pubmed/21589531 http://dx.doi.org/10.1107/S1600536810047604 Text en © Vilela et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Vilela, Sérgio M. F. Almeida Paz, Filipe A. Tomé, João P. C. de Zea Bermudez, Verónica Cavaleiro, José A. S. Rocha, João Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title | Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title_full | Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title_fullStr | Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title_full_unstemmed | Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title_short | Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| title_sort | trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011776/ https://www.ncbi.nlm.nih.gov/pubmed/21589531 http://dx.doi.org/10.1107/S1600536810047604 |
| work_keys_str_mv | AT vilelasergiomf trimethyl222135triazine246triyltrisazanediyltriacetate AT almeidapazfilipea trimethyl222135triazine246triyltrisazanediyltriacetate AT tomejoaopc trimethyl222135triazine246triyltrisazanediyltriacetate AT dezeabermudezveronica trimethyl222135triazine246triyltrisazanediyltriacetate AT cavaleirojoseas trimethyl222135triazine246triyltrisazanediyltriacetate AT rochajoao trimethyl222135triazine246triyltrisazanediyltriacetate |