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Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate

The complex mol­ecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methyl­idene­amino]-2-hy­droxy­benzoate anions and coordinated by two water mol­e...

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Detalles Bibliográficos
Autores principales: Bing, Yue, Li, Xing, Zha, Meiqin, Lu, Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011778/
https://www.ncbi.nlm.nih.gov/pubmed/21589225
http://dx.doi.org/10.1107/S160053681004496X
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author Bing, Yue
Li, Xing
Zha, Meiqin
Lu, Yue
author_facet Bing, Yue
Li, Xing
Zha, Meiqin
Lu, Yue
author_sort Bing, Yue
collection PubMed
description The complex mol­ecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methyl­idene­amino]-2-hy­droxy­benzoate anions and coordinated by two water mol­ecules in a distorted octa­hedral geometry. Within the anionic ligand, the pyridine ring is oriented at a dihedral angle of 49.54 (10)° with respect to the benzene ring. The carboxyl­ate group of the anionic ligand is not involved in coordination but is O—H⋯O hydrogen bonded to the coordinated and uncoordinated water mol­ecules. Weak inter­molecular C—H⋯O hydrogen bonding is also present in the crystal structure.
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spelling pubmed-30117782010-12-30 Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate Bing, Yue Li, Xing Zha, Meiqin Lu, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methyl­idene­amino]-2-hy­droxy­benzoate anions and coordinated by two water mol­ecules in a distorted octa­hedral geometry. Within the anionic ligand, the pyridine ring is oriented at a dihedral angle of 49.54 (10)° with respect to the benzene ring. The carboxyl­ate group of the anionic ligand is not involved in coordination but is O—H⋯O hydrogen bonded to the coordinated and uncoordinated water mol­ecules. Weak inter­molecular C—H⋯O hydrogen bonding is also present in the crystal structure. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011778/ /pubmed/21589225 http://dx.doi.org/10.1107/S160053681004496X Text en © Bing et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bing, Yue
Li, Xing
Zha, Meiqin
Lu, Yue
Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title_full Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title_fullStr Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title_full_unstemmed Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title_short Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}zinc(II) dihydrate
title_sort diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) n,n′}zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011778/
https://www.ncbi.nlm.nih.gov/pubmed/21589225
http://dx.doi.org/10.1107/S160053681004496X
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