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Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2) N,N′}zinc(II) dihydrate
The complex molecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methylideneamino]-2-hydroxybenzoate anions and coordinated by two water mole...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011778/ https://www.ncbi.nlm.nih.gov/pubmed/21589225 http://dx.doi.org/10.1107/S160053681004496X |
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author | Bing, Yue Li, Xing Zha, Meiqin Lu, Yue |
author_facet | Bing, Yue Li, Xing Zha, Meiqin Lu, Yue |
author_sort | Bing, Yue |
collection | PubMed |
description | The complex molecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methylideneamino]-2-hydroxybenzoate anions and coordinated by two water molecules in a distorted octahedral geometry. Within the anionic ligand, the pyridine ring is oriented at a dihedral angle of 49.54 (10)° with respect to the benzene ring. The carboxylate group of the anionic ligand is not involved in coordination but is O—H⋯O hydrogen bonded to the coordinated and uncoordinated water molecules. Weak intermolecular C—H⋯O hydrogen bonding is also present in the crystal structure. |
format | Text |
id | pubmed-3011778 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117782010-12-30 Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2) N,N′}zinc(II) dihydrate Bing, Yue Li, Xing Zha, Meiqin Lu, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex molecule of the title compound, [Zn(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, has 2 symmetry with the Zn(II) cation located on a twofold rotation axis. The Zn cation is N,N′-chelated by two 5-[(pyridin-2-yl)methylideneamino]-2-hydroxybenzoate anions and coordinated by two water molecules in a distorted octahedral geometry. Within the anionic ligand, the pyridine ring is oriented at a dihedral angle of 49.54 (10)° with respect to the benzene ring. The carboxylate group of the anionic ligand is not involved in coordination but is O—H⋯O hydrogen bonded to the coordinated and uncoordinated water molecules. Weak intermolecular C—H⋯O hydrogen bonding is also present in the crystal structure. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011778/ /pubmed/21589225 http://dx.doi.org/10.1107/S160053681004496X Text en © Bing et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bing, Yue Li, Xing Zha, Meiqin Lu, Yue Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2) N,N′}zinc(II) dihydrate |
title | Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
N,N′}zinc(II) dihydrate |
title_full | Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
N,N′}zinc(II) dihydrate |
title_fullStr | Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
N,N′}zinc(II) dihydrate |
title_full_unstemmed | Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
N,N′}zinc(II) dihydrate |
title_short | Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
N,N′}zinc(II) dihydrate |
title_sort | diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ(2)
n,n′}zinc(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011778/ https://www.ncbi.nlm.nih.gov/pubmed/21589225 http://dx.doi.org/10.1107/S160053681004496X |
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