4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate

In the title compound, C(13)H(10)N(4)O(5)·0.5C(2)H(5)OH, the two benzene rings form a dihedral angle of 4.29 (9)°. The ethanol solvent mol­ecule was treated as disordered between two orientations related by symmetry (center of inversion), with occupancies fixed at 0.5. The crystal packing, stabilize...

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Autor principal: Zhai, Xiu-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011783/
https://www.ncbi.nlm.nih.gov/pubmed/21589441
http://dx.doi.org/10.1107/S1600536810045782
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author Zhai, Xiu-Rong
author_facet Zhai, Xiu-Rong
author_sort Zhai, Xiu-Rong
collection PubMed
description In the title compound, C(13)H(10)N(4)O(5)·0.5C(2)H(5)OH, the two benzene rings form a dihedral angle of 4.29 (9)°. The ethanol solvent mol­ecule was treated as disordered between two orientations related by symmetry (center of inversion), with occupancies fixed at 0.5. The crystal packing, stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions [indicated by the short distance of 3.7299 (7) Å between the centroids of benzene rings from neighbouring mol­ecules], exhibits short inter­molecular O⋯O contacts of 2.8226 (3) Å.
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spelling pubmed-30117832010-12-30 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate Zhai, Xiu-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(4)O(5)·0.5C(2)H(5)OH, the two benzene rings form a dihedral angle of 4.29 (9)°. The ethanol solvent mol­ecule was treated as disordered between two orientations related by symmetry (center of inversion), with occupancies fixed at 0.5. The crystal packing, stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions [indicated by the short distance of 3.7299 (7) Å between the centroids of benzene rings from neighbouring mol­ecules], exhibits short inter­molecular O⋯O contacts of 2.8226 (3) Å. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011783/ /pubmed/21589441 http://dx.doi.org/10.1107/S1600536810045782 Text en © Xiu-Rong Zhai 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhai, Xiu-Rong
4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title_full 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title_fullStr 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title_full_unstemmed 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title_short 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
title_sort 4-{[2-(2,4-dinitro­phen­yl)hydrazinyl­idene]meth­yl}phenol ethanol hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011783/
https://www.ncbi.nlm.nih.gov/pubmed/21589441
http://dx.doi.org/10.1107/S1600536810045782
work_keys_str_mv AT zhaixiurong 4224dinitrophenylhydrazinylidenemethylphenolethanolhemisolvate

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