(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]

In the title compound, [Cu(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN(4) square-planar geometry. Two O,O′-bis­(4-methyl­phen­yl)dithio­phosphate anions occupy the axial positions with long Cu⋯S di...

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Detalles Bibliográficos
Autores principales: Zou, Li-Ke, Xie, Bin, Feng, Jian-Shen, Lai, Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011789/
https://www.ncbi.nlm.nih.gov/pubmed/21589275
http://dx.doi.org/10.1107/S1600536810046672
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author Zou, Li-Ke
Xie, Bin
Feng, Jian-Shen
Lai, Chuan
author_facet Zou, Li-Ke
Xie, Bin
Feng, Jian-Shen
Lai, Chuan
author_sort Zou, Li-Ke
collection PubMed
description In the title compound, [Cu(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN(4) square-planar geometry. Two O,O′-bis­(4-methyl­phen­yl)dithio­phosphate anions occupy the axial positions with long Cu⋯S distances of 3.0090 (8) Å. Inter­molecular N—H⋯S and C—H⋯S hydrogen bonding is present between the anions and the cation.
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spelling pubmed-30117892010-12-30 (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate] Zou, Li-Ke Xie, Bin Feng, Jian-Shen Lai, Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN(4) square-planar geometry. Two O,O′-bis­(4-methyl­phen­yl)dithio­phosphate anions occupy the axial positions with long Cu⋯S distances of 3.0090 (8) Å. Inter­molecular N—H⋯S and C—H⋯S hydrogen bonding is present between the anions and the cation. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011789/ /pubmed/21589275 http://dx.doi.org/10.1107/S1600536810046672 Text en © Zou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zou, Li-Ke
Xie, Bin
Feng, Jian-Shen
Lai, Chuan
(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title_full (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title_fullStr (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title_full_unstemmed (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title_short (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl)dithio­phosphate]
title_sort (c-meso-n-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)copper(ii) bis­[o,o′-bis­(4-methyl­phen­yl)dithio­phosphate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011789/
https://www.ncbi.nlm.nih.gov/pubmed/21589275
http://dx.doi.org/10.1107/S1600536810046672
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