catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]

The asymmetric unit of the title compound, {[Ce(C(3)H(2)O(4))Cl(H(2)O)(3)]·0.5H(2)O}(n), contains a Ce(3+) atom coordinated by a chloride anion, three water mol­ecules and a malonate ligand, and one water mol­ecule of crystallization with a factor of occupancy of 50%. The malonate ligand is bonded t...

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Detalles Bibliográficos
Autores principales: Silva, Patrícia, Fernandes, José A., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011794/
https://www.ncbi.nlm.nih.gov/pubmed/21589218
http://dx.doi.org/10.1107/S1600536810044727
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author Silva, Patrícia
Fernandes, José A.
Almeida Paz, Filipe A.
author_facet Silva, Patrícia
Fernandes, José A.
Almeida Paz, Filipe A.
author_sort Silva, Patrícia
collection PubMed
description The asymmetric unit of the title compound, {[Ce(C(3)H(2)O(4))Cl(H(2)O)(3)]·0.5H(2)O}(n), contains a Ce(3+) atom coordinated by a chloride anion, three water mol­ecules and a malonate ligand, and one water mol­ecule of crystallization with a factor of occupancy of 50%. The malonate ligand is bonded to three different symmetry-related metal atoms yielding a one-dimensional coordination polymer running parallel to the a axis. A supra­molecular network composed of strong and highly directional O—H⋯O and O—H⋯Cl hydrogen bonds ensures a close and effective packing of adjacent polymeric chains.
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spelling pubmed-30117942010-12-30 catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate] Silva, Patrícia Fernandes, José A. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Ce(C(3)H(2)O(4))Cl(H(2)O)(3)]·0.5H(2)O}(n), contains a Ce(3+) atom coordinated by a chloride anion, three water mol­ecules and a malonate ligand, and one water mol­ecule of crystallization with a factor of occupancy of 50%. The malonate ligand is bonded to three different symmetry-related metal atoms yielding a one-dimensional coordination polymer running parallel to the a axis. A supra­molecular network composed of strong and highly directional O—H⋯O and O—H⋯Cl hydrogen bonds ensures a close and effective packing of adjacent polymeric chains. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011794/ /pubmed/21589218 http://dx.doi.org/10.1107/S1600536810044727 Text en © Silva et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Silva, Patrícia
Fernandes, José A.
Almeida Paz, Filipe A.
catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title_full catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title_fullStr catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title_full_unstemmed catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title_short catena-Poly[[triaqua­chlorido-μ(3)-malonato-cerium(III)] hemihydrate]
title_sort catena-poly[[triaqua­chlorido-μ(3)-malonato-cerium(iii)] hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011794/
https://www.ncbi.nlm.nih.gov/pubmed/21589218
http://dx.doi.org/10.1107/S1600536810044727
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