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Bis(4-cyano­phenolato)[hydro­tris­(3,5-dimethyl­pyrazol­yl)borato]nitro­syl­molybdenum(II)–4-hydroxy­benzonitrile–dichloro­methane (1/1/1)

In the title compound, [Mo(C(15)H(22)BN(6))(C(7)H(4)NO)(2)(NO)]·C(7)H(5)NO·CH(2)Cl(2), the central Mo(II) atom adopts a distorted cis-MoO(2)N(4) octa­hedral geometry with the hydro­tris­(3,5-dimethyl­pyrazolylborate) anion attached to the metal in an N,N′,N′′-tridentate tripodal coordination mode. T...

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Detalles Bibliográficos
Autores principales: Kassim, Mohammad B., McCleverty, Jon A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011797/
https://www.ncbi.nlm.nih.gov/pubmed/21589237
http://dx.doi.org/10.1107/S160053681004537X
Descripción
Sumario:In the title compound, [Mo(C(15)H(22)BN(6))(C(7)H(4)NO)(2)(NO)]·C(7)H(5)NO·CH(2)Cl(2), the central Mo(II) atom adopts a distorted cis-MoO(2)N(4) octa­hedral geometry with the hydro­tris­(3,5-dimethyl­pyrazolylborate) anion attached to the metal in an N,N′,N′′-tridentate tripodal coordination mode. Two O-bonded 4-cyano­phenolate anions and a nitrosyl cation complete the coodination of the Mo(II) atom. Two intra­molecular C—H⋯O and one C—H⋯N hydrogen bonds help to establish the configuration of the complex mol­ecule. The crystal structure is stabilized by inter­molecular C—H⋯N and C—H⋯O hydrogen bonds.