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Ethyl 4,6-O-benzyl­idene-2-de­oxy-N-phthalimido-1-thio-β-d-glucopyran­oside

In the title compound, C(23)H(23)NO(6)S, the plane of the N-phthalimido group makes a dihedral angle of 67.4 (1)° with the least square plane of the sugar ring defined by the C2, C3, C5 and O5 atoms using standard glucose nomenclature. The thio­ethyl group has the exo-anomeric conformation. In the c...

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Detalles Bibliográficos
Autores principales: Hamark, Christoffer, Landström, Jens, Eriksson, Lars, Widmalm, Göran
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011798/
https://www.ncbi.nlm.nih.gov/pubmed/21589535
http://dx.doi.org/10.1107/S1600536810047070
Descripción
Sumario:In the title compound, C(23)H(23)NO(6)S, the plane of the N-phthalimido group makes a dihedral angle of 67.4 (1)° with the least square plane of the sugar ring defined by the C2, C3, C5 and O5 atoms using standard glucose nomenclature. The thio­ethyl group has the exo-anomeric conformation. In the crystal, inter­molecular hydrogen bonds involving the hy­droxy groups and the carbonyl O atoms of adjacent N-phthalimido groups form chains parallel to the b axis. The chains are further stabilized by C—H⋯π inter­actions.