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1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)

In the mol­ecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethyl­amino group and one Tip ligand (Tip = 2,4,6-triisopropyl­phen­yl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on...

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Detalles Bibliográficos
Autores principales: Braunschweig, Holger, Damme, Alexander
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011803/
https://www.ncbi.nlm.nih.gov/pubmed/21589635
http://dx.doi.org/10.1107/S1600536810049500
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author Braunschweig, Holger
Damme, Alexander
author_facet Braunschweig, Holger
Damme, Alexander
author_sort Braunschweig, Holger
collection PubMed
description In the mol­ecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethyl­amino group and one Tip ligand (Tip = 2,4,6-triisopropyl­phen­yl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B—B separation but not on the overall geometry of the title compound.
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spelling pubmed-30118032010-12-30 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4) Braunschweig, Holger Damme, Alexander Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethyl­amino group and one Tip ligand (Tip = 2,4,6-triisopropyl­phen­yl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B—B separation but not on the overall geometry of the title compound. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011803/ /pubmed/21589635 http://dx.doi.org/10.1107/S1600536810049500 Text en © Braunschweig and Damme 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Braunschweig, Holger
Damme, Alexander
1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title_full 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title_fullStr 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title_full_unstemmed 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title_short 1,2-Bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
title_sort 1,2-bis(dimethyl­amino)-1,2-bis­(2,4,6-triisopropyl­phen­yl)diborane(4)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011803/
https://www.ncbi.nlm.nih.gov/pubmed/21589635
http://dx.doi.org/10.1107/S1600536810049500
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