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1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4)
In the molecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethylamino group and one Tip ligand (Tip = 2,4,6-triisopropylphenyl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011803/ https://www.ncbi.nlm.nih.gov/pubmed/21589635 http://dx.doi.org/10.1107/S1600536810049500 |
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author | Braunschweig, Holger Damme, Alexander |
author_facet | Braunschweig, Holger Damme, Alexander |
author_sort | Braunschweig, Holger |
collection | PubMed |
description | In the molecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethylamino group and one Tip ligand (Tip = 2,4,6-triisopropylphenyl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B—B separation but not on the overall geometry of the title compound. |
format | Text |
id | pubmed-3011803 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30118032010-12-30 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) Braunschweig, Holger Damme, Alexander Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecular structure of the title compound, C(34)H(58)B(2)N(2), each B atom of the diborane(4) is connected to one dimethylamino group and one Tip ligand (Tip = 2,4,6-triisopropylphenyl). These findings indicate that the increased steric demand of the Tip groups exerts influence solely on the B—B separation but not on the overall geometry of the title compound. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011803/ /pubmed/21589635 http://dx.doi.org/10.1107/S1600536810049500 Text en © Braunschweig and Damme 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Braunschweig, Holger Damme, Alexander 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title | 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title_full | 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title_fullStr | 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title_full_unstemmed | 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title_short | 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
title_sort | 1,2-bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011803/ https://www.ncbi.nlm.nih.gov/pubmed/21589635 http://dx.doi.org/10.1107/S1600536810049500 |
work_keys_str_mv | AT braunschweigholger 12bisdimethylamino12bis246triisopropylphenyldiborane4 AT dammealexander 12bisdimethylamino12bis246triisopropylphenyldiborane4 |