Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate

In the title complex, [Ni(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom, located on a twofold rotation axis, is in a distorted octa­hedral geometry, defined by four N atoms from two 2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoate ligands and two O atoms from two water mol­ecules....

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Detalles Bibliográficos
Autores principales: Zha, Meiqin, Li, Xing, Bing, Yue, Luo, Zhengbing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011804/
https://www.ncbi.nlm.nih.gov/pubmed/21589257
http://dx.doi.org/10.1107/S1600536810046118
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author Zha, Meiqin
Li, Xing
Bing, Yue
Luo, Zhengbing
author_facet Zha, Meiqin
Li, Xing
Bing, Yue
Luo, Zhengbing
author_sort Zha, Meiqin
collection PubMed
description In the title complex, [Ni(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom, located on a twofold rotation axis, is in a distorted octa­hedral geometry, defined by four N atoms from two 2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoate ligands and two O atoms from two water mol­ecules. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a three-dimensional network. Intra­molecular O—H⋯O hydrogen bonds are present between the hy­droxy and carboxyl­ate groups.
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spelling pubmed-30118042010-12-30 Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate Zha, Meiqin Li, Xing Bing, Yue Luo, Zhengbing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom, located on a twofold rotation axis, is in a distorted octa­hedral geometry, defined by four N atoms from two 2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoate ligands and two O atoms from two water mol­ecules. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a three-dimensional network. Intra­molecular O—H⋯O hydrogen bonds are present between the hy­droxy and carboxyl­ate groups. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011804/ /pubmed/21589257 http://dx.doi.org/10.1107/S1600536810046118 Text en © Zha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zha, Meiqin
Li, Xing
Bing, Yue
Luo, Zhengbing
Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title_full Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title_fullStr Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title_full_unstemmed Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title_short Diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) N,N′}nickel(II) dihydrate
title_sort diaqua­bis­{2-hy­droxy-5-[(pyridin-2-yl)methyl­idene­amino]­benzoato-κ(2) n,n′}nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011804/
https://www.ncbi.nlm.nih.gov/pubmed/21589257
http://dx.doi.org/10.1107/S1600536810046118
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AT lixing diaquabis2hydroxy5pyridin2ylmethylideneaminobenzoatok2nnnickeliidihydrate
AT bingyue diaquabis2hydroxy5pyridin2ylmethylideneaminobenzoatok2nnnickeliidihydrate
AT luozhengbing diaquabis2hydroxy5pyridin2ylmethylideneaminobenzoatok2nnnickeliidihydrate

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