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Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]

The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex mol­ecule, which lies about a crystallographic inversion centre with one half-mol­ecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms,...

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Detalles Bibliográficos
Autores principales: Zhao, Yan, Pan, Tonghen, Chen, Zhitao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011806/
https://www.ncbi.nlm.nih.gov/pubmed/21589330
http://dx.doi.org/10.1107/S1600536810048488
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author Zhao, Yan
Pan, Tonghen
Chen, Zhitao
author_facet Zhao, Yan
Pan, Tonghen
Chen, Zhitao
author_sort Zhao, Yan
collection PubMed
description The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex mol­ecule, which lies about a crystallographic inversion centre with one half-mol­ecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms, in a Jahn–Teller-distorted octa­hedral geometry. The basal plane is defined by the two N atoms from the 1,10-phenathroline and two deprotonated O atoms of the polycarboxyl­ate ligand. The axial positions are occupied by the azane N atom and a bridging carboxyl­ate O atom from the second polycarboxyl­ate ligand. The complex mol­ecules are linked through O—H⋯O hydrogen bonds into extended chains running parallel to [010].
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spelling pubmed-30118062010-12-30 Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)] Zhao, Yan Pan, Tonghen Chen, Zhitao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex mol­ecule, which lies about a crystallographic inversion centre with one half-mol­ecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms, in a Jahn–Teller-distorted octa­hedral geometry. The basal plane is defined by the two N atoms from the 1,10-phenathroline and two deprotonated O atoms of the polycarboxyl­ate ligand. The axial positions are occupied by the azane N atom and a bridging carboxyl­ate O atom from the second polycarboxyl­ate ligand. The complex mol­ecules are linked through O—H⋯O hydrogen bonds into extended chains running parallel to [010]. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011806/ /pubmed/21589330 http://dx.doi.org/10.1107/S1600536810048488 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Yan
Pan, Tonghen
Chen, Zhitao
Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title_full Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title_fullStr Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title_full_unstemmed Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title_short Bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(II)]
title_sort bis(μ-2,2′-{[4-(carb­oxy­meth­oxy)phen­yl]aza­nedi­yl}diacetato)­bis­[(1,10-phenanthroline)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011806/
https://www.ncbi.nlm.nih.gov/pubmed/21589330
http://dx.doi.org/10.1107/S1600536810048488
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