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Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)]
The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex molecule, which lies about a crystallographic inversion centre with one half-molecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms,...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011806/ https://www.ncbi.nlm.nih.gov/pubmed/21589330 http://dx.doi.org/10.1107/S1600536810048488 |
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author | Zhao, Yan Pan, Tonghen Chen, Zhitao |
author_facet | Zhao, Yan Pan, Tonghen Chen, Zhitao |
author_sort | Zhao, Yan |
collection | PubMed |
description | The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex molecule, which lies about a crystallographic inversion centre with one half-molecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms, in a Jahn–Teller-distorted octahedral geometry. The basal plane is defined by the two N atoms from the 1,10-phenathroline and two deprotonated O atoms of the polycarboxylate ligand. The axial positions are occupied by the azane N atom and a bridging carboxylate O atom from the second polycarboxylate ligand. The complex molecules are linked through O—H⋯O hydrogen bonds into extended chains running parallel to [010]. |
format | Text |
id | pubmed-3011806 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30118062010-12-30 Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] Zhao, Yan Pan, Tonghen Chen, Zhitao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex molecule, which lies about a crystallographic inversion centre with one half-molecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms, in a Jahn–Teller-distorted octahedral geometry. The basal plane is defined by the two N atoms from the 1,10-phenathroline and two deprotonated O atoms of the polycarboxylate ligand. The axial positions are occupied by the azane N atom and a bridging carboxylate O atom from the second polycarboxylate ligand. The complex molecules are linked through O—H⋯O hydrogen bonds into extended chains running parallel to [010]. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011806/ /pubmed/21589330 http://dx.doi.org/10.1107/S1600536810048488 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Yan Pan, Tonghen Chen, Zhitao Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title | Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title_full | Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title_fullStr | Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title_full_unstemmed | Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title_short | Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)] |
title_sort | bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011806/ https://www.ncbi.nlm.nih.gov/pubmed/21589330 http://dx.doi.org/10.1107/S1600536810048488 |
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