N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide

The title compound, C(9)H(9)N(3)O(3)S, comprises a racemic mixture of chiral mol­ecules containing four stereogenic centres. The cyclo­hexane ring tends towards a boat conformation, while the tetra­hydro­furan ring and the dihydro­furan ring adopt envelope conformations. The dihedral angle between t...

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Detalles Bibliográficos
Autor principal: Li, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011812/
https://www.ncbi.nlm.nih.gov/pubmed/21589603
http://dx.doi.org/10.1107/S160053681004835X
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author Li, Jian
author_facet Li, Jian
author_sort Li, Jian
collection PubMed
description The title compound, C(9)H(9)N(3)O(3)S, comprises a racemic mixture of chiral mol­ecules containing four stereogenic centres. The cyclo­hexane ring tends towards a boat conformation, while the tetra­hydro­furan ring and the dihydro­furan ring adopt envelope conformations. The dihedral angle between the thio­semicarbazide fragment and the fused-ring system is 77.20 (10)°. The crystal structure is stabilized by two inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-30118122010-12-30 N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide Li, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(9)N(3)O(3)S, comprises a racemic mixture of chiral mol­ecules containing four stereogenic centres. The cyclo­hexane ring tends towards a boat conformation, while the tetra­hydro­furan ring and the dihydro­furan ring adopt envelope conformations. The dihedral angle between the thio­semicarbazide fragment and the fused-ring system is 77.20 (10)°. The crystal structure is stabilized by two inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011812/ /pubmed/21589603 http://dx.doi.org/10.1107/S160053681004835X Text en © Jian Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jian
N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title_full N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title_fullStr N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title_full_unstemmed N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title_short N-Carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
title_sort n-carbamothioyl­amino-7-oxabicyclo­[2.2.1]hept-5-ene-2,3-dicarboximide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011812/
https://www.ncbi.nlm.nih.gov/pubmed/21589603
http://dx.doi.org/10.1107/S160053681004835X
work_keys_str_mv AT lijian ncarbamothioylamino7oxabicyclo221hept5ene23dicarboximide

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