Olefin metathesis in nano-sized systems

The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade. Two subjects are presented and discussed: (i) The catalysis of olefin metathesis by dendritic nano-catalysts via either...

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Detalles Bibliográficos
Autores principales: Astruc, Didier, Diallo, Abdou K, Gatard, Sylvain, Liang, Liyuan, Ornelas, Cátia, Martinez, Victor, Méry, Denise, Ruiz, Jaime
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3028528/
https://www.ncbi.nlm.nih.gov/pubmed/21286399
http://dx.doi.org/10.3762/bjoc.7.13
Descripción
Sumario:The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade. Two subjects are presented and discussed: (i) The catalysis of olefin metathesis by dendritic nano-catalysts via either covalent attachment (ROMP) or, more usefully, dendrimer encapsulation – ring closing metathesis (RCM), cross metathesis (CM), enyne metathesis reactions (EYM) – for reactions in water without a co-solvent and (ii) construction and functionalization of dendrimers by CM reactions.

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