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Synthesis of Ru alkylidene complexes

The present work describes the robust synthesis of Ru alkylidene complexes (PCy(3))(2)Cl(2)Ru=CHR – precursors for metathesis catalysts. Moreover, the dynamic behavior of complexes where R = 2-naphthyl and 2-thienyl was studied. (1)H NMR techniques were employed to establish the preferred conformati...

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Detalles Bibliográficos
Autores principales: Kadyrov, Renat, Rosiak, Anna
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3028570/
https://www.ncbi.nlm.nih.gov/pubmed/21286400
http://dx.doi.org/10.3762/bjoc.7.14