Thermal rearrangement of tert-butylsulfinamide

tert-Butylsulfinamides are unstable above room temperature, and in chlorinated solvents they undergo rearrangement to form the more stable N-(tert-butylthio)-tert-butylsulfonamide.

Detalles Bibliográficos
Autores principales: Arava, Veera Reddy, Gorentla, Laxminarasimhulu, Dubey, Pramod Kumar
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3028921/
https://www.ncbi.nlm.nih.gov/pubmed/21286388
http://dx.doi.org/10.3762/bjoc.7.2
Descripción
Sumario:tert-Butylsulfinamides are unstable above room temperature, and in chlorinated solvents they undergo rearrangement to form the more stable N-(tert-butylthio)-tert-butylsulfonamide.

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