Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization

Flexible and asymmetric ligand L [L = 1-((pyridin-3-yl)methyl)-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag(2)(L)(2)(NO(3))(2)](n) (1) and [Ag(L)(ClO(4))](n) (2), were synthesized and characterized by X-ray structure...

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Autores principales: Chen, Peng, Lin, Jianhua
Formato: Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3039942/
https://www.ncbi.nlm.nih.gov/pubmed/21339976
http://dx.doi.org/10.3390/ijms12010046
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author Chen, Peng
Lin, Jianhua
author_facet Chen, Peng
Lin, Jianhua
author_sort Chen, Peng
collection PubMed
description Flexible and asymmetric ligand L [L = 1-((pyridin-3-yl)methyl)-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag(2)(L)(2)(NO(3))(2)](n) (1) and [Ag(L)(ClO(4))](n) (2), were synthesized and characterized by X-ray structure analysis and fluorescent spectroscopy. The complex 1 gives an “S” type double helical conformation, whereas complex 2 exhibits a 1D zigzag configuration. Different anions affect the silver coordination geometry and crystal packing topology.
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spelling pubmed-30399422011-02-18 Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization Chen, Peng Lin, Jianhua Int J Mol Sci Article Flexible and asymmetric ligand L [L = 1-((pyridin-3-yl)methyl)-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag(2)(L)(2)(NO(3))(2)](n) (1) and [Ag(L)(ClO(4))](n) (2), were synthesized and characterized by X-ray structure analysis and fluorescent spectroscopy. The complex 1 gives an “S” type double helical conformation, whereas complex 2 exhibits a 1D zigzag configuration. Different anions affect the silver coordination geometry and crystal packing topology. Molecular Diversity Preservation International (MDPI) 2010-12-27 /pmc/articles/PMC3039942/ /pubmed/21339976 http://dx.doi.org/10.3390/ijms12010046 Text en © 2011 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0 This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Chen, Peng
Lin, Jianhua
Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title_full Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title_fullStr Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title_full_unstemmed Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title_short Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization
title_sort flexible and asymmetric ligand in constructing coordinated complexes: synthesis, crystal structures and fluorescent characterization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3039942/
https://www.ncbi.nlm.nih.gov/pubmed/21339976
http://dx.doi.org/10.3390/ijms12010046
work_keys_str_mv AT chenpeng flexibleandasymmetricligandinconstructingcoordinatedcomplexessynthesiscrystalstructuresandfluorescentcharacterization
AT linjianhua flexibleandasymmetricligandinconstructingcoordinatedcomplexessynthesiscrystalstructuresandfluorescentcharacterization

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