N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)

The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra­chlorido­cobalt­ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (...

Descripción completa

Detalles Bibliográficos
Autores principales: Baughman, Russell G., Shane, Rebecca S., McCormick, James M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050123/
https://www.ncbi.nlm.nih.gov/pubmed/21522515
http://dx.doi.org/10.1107/S1600536810048749
_version_ 1782199289886277632
author Baughman, Russell G.
Shane, Rebecca S.
McCormick, James M.
author_facet Baughman, Russell G.
Shane, Rebecca S.
McCormick, James M.
author_sort Baughman, Russell G.
collection PubMed
description The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra­chlorido­cobalt­ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (13):0.216 (13) ratio. In the crystal, inter­molecular N—H⋯Cl hydrogen bonds link cations and anions into chains propagated in [0[Image: see text]1]. These hydrogen bonds contribute to the distorted tetra­hedral geometry at the Co(II) atom.
format Text
id pubmed-3050123
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30501232011-04-26 N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II) Baughman, Russell G. Shane, Rebecca S. McCormick, James M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra­chlorido­cobalt­ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (13):0.216 (13) ratio. In the crystal, inter­molecular N—H⋯Cl hydrogen bonds link cations and anions into chains propagated in [0[Image: see text]1]. These hydrogen bonds contribute to the distorted tetra­hedral geometry at the Co(II) atom. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050123/ /pubmed/21522515 http://dx.doi.org/10.1107/S1600536810048749 Text en © Baughman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baughman, Russell G.
Shane, Rebecca S.
McCormick, James M.
N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title_full N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title_fullStr N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title_full_unstemmed N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title_short N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)
title_sort n,n,n′,n′-tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050123/
https://www.ncbi.nlm.nih.gov/pubmed/21522515
http://dx.doi.org/10.1107/S1600536810048749
work_keys_str_mv AT baughmanrussellg nnnntetramethylethylenediammoniumtetrachloridocobaltateii
AT shanerebeccas nnnntetramethylethylenediammoniumtetrachloridocobaltateii
AT mccormickjamesm nnnntetramethylethylenediammoniumtetrachloridocobaltateii

Ejemplares similares