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Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thiazole-κ(2) N,N′)mercury(II)
The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent molecules. The Hg(II) atoms are four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and two Br atoms. In the cryst...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050124/ https://www.ncbi.nlm.nih.gov/pubmed/21522594 http://dx.doi.org/10.1107/S1600536810051494 |
Sumario: | The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent molecules. The Hg(II) atoms are four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and two Br atoms. In the crystal structure, intermolecular C—H⋯Br hydrogen bonds and π–π contacts between the thiazole rings [centroid–centroid distances = 3.670 (3) and 3.614 (2) Å] stabilize the structure. |
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