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Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)

The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol­ecules. The Hg(II) atoms are four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and two Br atoms. In the cryst...

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Detalles Bibliográficos
Autor principal: Abedi, Anita
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050124/
https://www.ncbi.nlm.nih.gov/pubmed/21522594
http://dx.doi.org/10.1107/S1600536810051494
Descripción
Sumario:The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol­ecules. The Hg(II) atoms are four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and two Br atoms. In the crystal structure, inter­molecular C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.670 (3) and 3.614 (2) Å] stabilize the structure.