Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)

The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol­ecules. The Hg(II) atoms are four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and two Br atoms. In the cryst...

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Detalles Bibliográficos
Autor principal: Abedi, Anita
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050124/
https://www.ncbi.nlm.nih.gov/pubmed/21522594
http://dx.doi.org/10.1107/S1600536810051494
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author Abedi, Anita
author_facet Abedi, Anita
author_sort Abedi, Anita
collection PubMed
description The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol­ecules. The Hg(II) atoms are four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and two Br atoms. In the crystal structure, inter­molecular C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.670 (3) and 3.614 (2) Å] stabilize the structure.
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spelling pubmed-30501242011-04-26 Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II) Abedi, Anita Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol­ecules. The Hg(II) atoms are four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and two Br atoms. In the crystal structure, inter­molecular C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.670 (3) and 3.614 (2) Å] stabilize the structure. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050124/ /pubmed/21522594 http://dx.doi.org/10.1107/S1600536810051494 Text en © Anita Abedi 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abedi, Anita
Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title_full Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title_fullStr Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title_full_unstemmed Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title_short Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)mercury(II)
title_sort dibromido(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050124/
https://www.ncbi.nlm.nih.gov/pubmed/21522594
http://dx.doi.org/10.1107/S1600536810051494
work_keys_str_mv AT abedianita dibromido22dimethyl44bi13thiazolek2nnmercuryii

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