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19-Benzoyloxy-13,16-seco-ent-beyeran 13,16-lactone
The title compound, C(27)H(34)O(5), a beyerane-type diterpenoid prepared by peroxidation and benzoylation of isosteviol, contains a fused six-membered ring system. The O atoms of the benzoic ester and the lactone are disordered with occupancy ratios of 0.6 (4):0.4 (4) and 0.6 (2):0.4 (2), respectiv...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050127/ https://www.ncbi.nlm.nih.gov/pubmed/21522644 http://dx.doi.org/10.1107/S1600536810051561 |
| Sumario: | The title compound, C(27)H(34)O(5), a beyerane-type diterpenoid prepared by peroxidation and benzoylation of isosteviol, contains a fused six-membered ring system. The O atoms of the benzoic ester and the lactone are disordered with occupancy ratios of 0.6 (4):0.4 (4) and 0.6 (2):0.4 (2), respectively. Three cyclohexane rings have chair conformations, whereas the remaining lactone ring adopts a half-chair conformation. |
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