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(E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide
In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are interconnected by N—H⋯S and N—H⋯F hydrogen bonds. There are two different N—H⋯S hydrogen bond: the stronger one links molecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N—H⋯S hydrogen...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050128/ https://www.ncbi.nlm.nih.gov/pubmed/21522787 http://dx.doi.org/10.1107/S1600536810051093 |
Sumario: | In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are interconnected by N—H⋯S and N—H⋯F hydrogen bonds. There are two different N—H⋯S hydrogen bond: the stronger one links molecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N—H⋯S hydrogen bond combines with the previous one into an R (2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N—H⋯F hydrogen bonds, which form an R (2) (2)(22) ring motif. In addition, there are also weak π–π interactions between the benzene rings of adjacent molecules [centroid–centroid distance = 3.8997 (15) Å]. |
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