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(E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide
In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are interconnected by N—H⋯S and N—H⋯F hydrogen bonds. There are two different N—H⋯S hydrogen bond: the stronger one links molecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N—H⋯S hydrogen...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050128/ https://www.ncbi.nlm.nih.gov/pubmed/21522787 http://dx.doi.org/10.1107/S1600536810051093 |
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author | Zhai, Xiu-Rong |
author_facet | Zhai, Xiu-Rong |
author_sort | Zhai, Xiu-Rong |
collection | PubMed |
description | In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are interconnected by N—H⋯S and N—H⋯F hydrogen bonds. There are two different N—H⋯S hydrogen bond: the stronger one links molecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N—H⋯S hydrogen bond combines with the previous one into an R (2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N—H⋯F hydrogen bonds, which form an R (2) (2)(22) ring motif. In addition, there are also weak π–π interactions between the benzene rings of adjacent molecules [centroid–centroid distance = 3.8997 (15) Å]. |
format | Text |
id | pubmed-3050128 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501282011-04-26 (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide Zhai, Xiu-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are interconnected by N—H⋯S and N—H⋯F hydrogen bonds. There are two different N—H⋯S hydrogen bond: the stronger one links molecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N—H⋯S hydrogen bond combines with the previous one into an R (2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N—H⋯F hydrogen bonds, which form an R (2) (2)(22) ring motif. In addition, there are also weak π–π interactions between the benzene rings of adjacent molecules [centroid–centroid distance = 3.8997 (15) Å]. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050128/ /pubmed/21522787 http://dx.doi.org/10.1107/S1600536810051093 Text en © Xiu-Rong Zhai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhai, Xiu-Rong (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title | (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title_full | (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title_fullStr | (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title_full_unstemmed | (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title_short | (E)-2-[1-(3-Chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
title_sort | (e)-2-[1-(3-chloro-4-fluorophenyl)ethylidene]hydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050128/ https://www.ncbi.nlm.nih.gov/pubmed/21522787 http://dx.doi.org/10.1107/S1600536810051093 |
work_keys_str_mv | AT zhaixiurong e213chloro4fluorophenylethylidenehydrazinecarbothioamide |