cis-(Pyridin-2-ylcarbonimidodithio­ato-κ(2) S,S′)bis­(triphenyl­phosphane-κP)palladium(II)

The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis­(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately...

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Detalles Bibliográficos
Autores principales: Bon, Vladimir V., Orysyk, Svitlana I., Pekhnyo, Vasily I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050130/
https://www.ncbi.nlm.nih.gov/pubmed/21522566
http://dx.doi.org/10.1107/S1600536810050518
Descripción
Sumario:The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis­(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio­ate ligand and two triphenyl­phosphine mol­ecules, coordinated in cis positions. The crystal structure features weak π–π [centroid–centroid distance =3.7327(15) Å] and C–H⋯π inter­actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.

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