2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one

The title compound, C(20)H(16)N(2)O(4)S, was prepared by introduction of a 2-nitro­benzyl group to 2-(furan-2-yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one via an alkaline-catalysed reaction. The thia­zepine ring adopts a twist-boat conformation. The furan ring is oriented at dihedral angles of 56.7...

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Detalles Bibliográficos
Autores principales: Huang, Zhao-Hui, Chu, Yong, Ye, De-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050135/
https://www.ncbi.nlm.nih.gov/pubmed/21522675
http://dx.doi.org/10.1107/S1600536810052098
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author Huang, Zhao-Hui
Chu, Yong
Ye, De-Yong
author_facet Huang, Zhao-Hui
Chu, Yong
Ye, De-Yong
author_sort Huang, Zhao-Hui
collection PubMed
description The title compound, C(20)H(16)N(2)O(4)S, was prepared by introduction of a 2-nitro­benzyl group to 2-(furan-2-yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one via an alkaline-catalysed reaction. The thia­zepine ring adopts a twist-boat conformation. The furan ring is oriented at dihedral angles of 56.75 (14) and 10.82 (14)° with respect to the two benzene rings, while the two benzene rings make a dihedral angle of 62.96 (10)°. Weak inter­molecular C—H⋯O hydrogen bonds occur in the crystal structure.
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spelling pubmed-30501352011-04-26 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one Huang, Zhao-Hui Chu, Yong Ye, De-Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)N(2)O(4)S, was prepared by introduction of a 2-nitro­benzyl group to 2-(furan-2-yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one via an alkaline-catalysed reaction. The thia­zepine ring adopts a twist-boat conformation. The furan ring is oriented at dihedral angles of 56.75 (14) and 10.82 (14)° with respect to the two benzene rings, while the two benzene rings make a dihedral angle of 62.96 (10)°. Weak inter­molecular C—H⋯O hydrogen bonds occur in the crystal structure. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050135/ /pubmed/21522675 http://dx.doi.org/10.1107/S1600536810052098 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Zhao-Hui
Chu, Yong
Ye, De-Yong
2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title_full 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title_fullStr 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title_full_unstemmed 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title_short 2-(Furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5H)-one
title_sort 2-(furan-2-yl)-5-(2-nitro­benz­yl)-2,3-dihydro-1,5-benzothia­zepin-4(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050135/
https://www.ncbi.nlm.nih.gov/pubmed/21522675
http://dx.doi.org/10.1107/S1600536810052098
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AT chuyong 2furan2yl52nitrobenzyl23dihydro15benzothiazepin45hone
AT yedeyong 2furan2yl52nitrobenzyl23dihydro15benzothiazepin45hone

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