{2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)

In the title compound, [Cu(C(19)H(12)N(5))(C(2)N(3))(CH(3)OH)], the Cu(II) atom is coordinated by three N atoms from an anionic 2,6-bis­(1H-benzimidazol-2-yl)pyridine (bbp) ligand, an O atom from a methanol mol­ecule and one N atom from a dicyanamide anion. The crystal structure is stabilized by O—H...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Jingchun, Zhang, Jinfang, Zhang, Weiming, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050137/
https://www.ncbi.nlm.nih.gov/pubmed/21522580
http://dx.doi.org/10.1107/S1600536810050178
_version_ 1782199293228089344
author Hu, Jingchun
Zhang, Jinfang
Zhang, Weiming
Zhang, Chi
author_facet Hu, Jingchun
Zhang, Jinfang
Zhang, Weiming
Zhang, Chi
author_sort Hu, Jingchun
collection PubMed
description In the title compound, [Cu(C(19)H(12)N(5))(C(2)N(3))(CH(3)OH)], the Cu(II) atom is coordinated by three N atoms from an anionic 2,6-bis­(1H-benzimidazol-2-yl)pyridine (bbp) ligand, an O atom from a methanol mol­ecule and one N atom from a dicyanamide anion. The crystal structure is stabilized by O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional network.
format Text
id pubmed-3050137
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30501372011-04-26 {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II) Hu, Jingchun Zhang, Jinfang Zhang, Weiming Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(19)H(12)N(5))(C(2)N(3))(CH(3)OH)], the Cu(II) atom is coordinated by three N atoms from an anionic 2,6-bis­(1H-benzimidazol-2-yl)pyridine (bbp) ligand, an O atom from a methanol mol­ecule and one N atom from a dicyanamide anion. The crystal structure is stabilized by O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050137/ /pubmed/21522580 http://dx.doi.org/10.1107/S1600536810050178 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Jingchun
Zhang, Jinfang
Zhang, Weiming
Zhang, Chi
{2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title_full {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title_fullStr {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title_full_unstemmed {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title_short {2-[6-(1H-Benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
title_sort {2-[6-(1h-benzimidazol-2-yl-κn (3))-2-pyridyl-κn]benzimidazolato-κn}(dicyanamido-κn)(methanol-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050137/
https://www.ncbi.nlm.nih.gov/pubmed/21522580
http://dx.doi.org/10.1107/S1600536810050178
work_keys_str_mv AT hujingchun 261hbenzimidazol2ylkn32pyridylknbenzimidazolatokndicyanamidoknmethanolkocopperii
AT zhangjinfang 261hbenzimidazol2ylkn32pyridylknbenzimidazolatokndicyanamidoknmethanolkocopperii
AT zhangweiming 261hbenzimidazol2ylkn32pyridylknbenzimidazolatokndicyanamidoknmethanolkocopperii
AT zhangchi 261hbenzimidazol2ylkn32pyridylknbenzimidazolatokndicyanamidoknmethanolkocopperii

Ejemplares similares