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2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate
In the title compound, C(21)H(21)N(5)O(4)S·0.5C(3)H(7)NO, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.451 (5) and 0.233 (5) Å, respectively, from the plane formed by the remaining ring atoms. The asymmetric unit contains a disordered half-...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050140/ https://www.ncbi.nlm.nih.gov/pubmed/21522716 http://dx.doi.org/10.1107/S1600536810052177 |
| _version_ | 1782199293934829568 |
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| author | Ahmad, Matloob Siddiqui, Hamid Latif Khattak, Manzoor Iqbal Ahmad, Saeed Parvez, Masood |
| author_facet | Ahmad, Matloob Siddiqui, Hamid Latif Khattak, Manzoor Iqbal Ahmad, Saeed Parvez, Masood |
| author_sort | Ahmad, Matloob |
| collection | PubMed |
| description | In the title compound, C(21)H(21)N(5)O(4)S·0.5C(3)H(7)NO, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.451 (5) and 0.233 (5) Å, respectively, from the plane formed by the remaining ring atoms. The asymmetric unit contains a disordered half-molecule of solvent lying close to inversion centers. The crystal structure is stabilized by weak intermolecular N—H⋯O and C—H⋯O interactions. |
| format | Text |
| id | pubmed-3050140 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30501402011-04-26 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate Ahmad, Matloob Siddiqui, Hamid Latif Khattak, Manzoor Iqbal Ahmad, Saeed Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)N(5)O(4)S·0.5C(3)H(7)NO, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.451 (5) and 0.233 (5) Å, respectively, from the plane formed by the remaining ring atoms. The asymmetric unit contains a disordered half-molecule of solvent lying close to inversion centers. The crystal structure is stabilized by weak intermolecular N—H⋯O and C—H⋯O interactions. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050140/ /pubmed/21522716 http://dx.doi.org/10.1107/S1600536810052177 Text en © Ahmad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Ahmad, Matloob Siddiqui, Hamid Latif Khattak, Manzoor Iqbal Ahmad, Saeed Parvez, Masood 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title | 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title_full | 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title_fullStr | 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title_full_unstemmed | 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title_short | 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| title_sort | 2-(3,4-dimethyl-5,5-dioxo-2h,4h-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-n′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050140/ https://www.ncbi.nlm.nih.gov/pubmed/21522716 http://dx.doi.org/10.1107/S1600536810052177 |
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