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2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine

The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetyl­pyridine and 1,3-diamino­propane. It crystallizes with two independent mol­ecules in the asymmetric unit with different conformations. In the first mol­ecule, the methyl groups are cis oriented with respect to the p...

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Detalles Bibliográficos
Autores principales: Ton, Quoc-Cuong, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050144/
https://www.ncbi.nlm.nih.gov/pubmed/21522750
http://dx.doi.org/10.1107/S1600536810050063
Descripción
Sumario:The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetyl­pyridine and 1,3-diamino­propane. It crystallizes with two independent mol­ecules in the asymmetric unit with different conformations. In the first mol­ecule, the methyl groups are cis oriented with respect to the pyridine ring [N—C—C—C torsion angles = 72.5 (1) and 80.3 (1)°], while they are trans oriented in the second mol­ecule [N—C—C—C torsion angles = 82.6 (1) and −90.8 (1)°]. Each of the two mol­ecules forms centrosymmetric dimers held together by N—H⋯N hydrogen bonds, thus forming R (2) (2)(16) rings. The two dimers are inter­linked by additional N—H⋯N bonds into R (4) (4)(14) rings, building chains along the a axis. These patterns influence the orientation (either equatorial or axial) of the N—H bonds.