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2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine
The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetylpyridine and 1,3-diaminopropane. It crystallizes with two independent molecules in the asymmetric unit with different conformations. In the first molecule, the methyl groups are cis oriented with respect to the p...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050144/ https://www.ncbi.nlm.nih.gov/pubmed/21522750 http://dx.doi.org/10.1107/S1600536810050063 |
Sumario: | The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetylpyridine and 1,3-diaminopropane. It crystallizes with two independent molecules in the asymmetric unit with different conformations. In the first molecule, the methyl groups are cis oriented with respect to the pyridine ring [N—C—C—C torsion angles = 72.5 (1) and 80.3 (1)°], while they are trans oriented in the second molecule [N—C—C—C torsion angles = 82.6 (1) and −90.8 (1)°]. Each of the two molecules forms centrosymmetric dimers held together by N—H⋯N hydrogen bonds, thus forming R (2) (2)(16) rings. The two dimers are interlinked by additional N—H⋯N bonds into R (4) (4)(14) rings, building chains along the a axis. These patterns influence the orientation (either equatorial or axial) of the N—H bonds. |
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