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2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine
The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetylpyridine and 1,3-diaminopropane. It crystallizes with two independent molecules in the asymmetric unit with different conformations. In the first molecule, the methyl groups are cis oriented with respect to the p...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050144/ https://www.ncbi.nlm.nih.gov/pubmed/21522750 http://dx.doi.org/10.1107/S1600536810050063 |
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author | Ton, Quoc-Cuong Bolte, Michael |
author_facet | Ton, Quoc-Cuong Bolte, Michael |
author_sort | Ton, Quoc-Cuong |
collection | PubMed |
description | The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetylpyridine and 1,3-diaminopropane. It crystallizes with two independent molecules in the asymmetric unit with different conformations. In the first molecule, the methyl groups are cis oriented with respect to the pyridine ring [N—C—C—C torsion angles = 72.5 (1) and 80.3 (1)°], while they are trans oriented in the second molecule [N—C—C—C torsion angles = 82.6 (1) and −90.8 (1)°]. Each of the two molecules forms centrosymmetric dimers held together by N—H⋯N hydrogen bonds, thus forming R (2) (2)(16) rings. The two dimers are interlinked by additional N—H⋯N bonds into R (4) (4)(14) rings, building chains along the a axis. These patterns influence the orientation (either equatorial or axial) of the N—H bonds. |
format | Text |
id | pubmed-3050144 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501442011-04-26 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine Ton, Quoc-Cuong Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(25)N(5), is an aminalization product between 2,6-diacetylpyridine and 1,3-diaminopropane. It crystallizes with two independent molecules in the asymmetric unit with different conformations. In the first molecule, the methyl groups are cis oriented with respect to the pyridine ring [N—C—C—C torsion angles = 72.5 (1) and 80.3 (1)°], while they are trans oriented in the second molecule [N—C—C—C torsion angles = 82.6 (1) and −90.8 (1)°]. Each of the two molecules forms centrosymmetric dimers held together by N—H⋯N hydrogen bonds, thus forming R (2) (2)(16) rings. The two dimers are interlinked by additional N—H⋯N bonds into R (4) (4)(14) rings, building chains along the a axis. These patterns influence the orientation (either equatorial or axial) of the N—H bonds. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050144/ /pubmed/21522750 http://dx.doi.org/10.1107/S1600536810050063 Text en © Ton and Bolte 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ton, Quoc-Cuong Bolte, Michael 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title | 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title_full | 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title_fullStr | 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title_full_unstemmed | 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title_short | 2,6-Bis(2-methyl-1,3-diazinan-2-yl)pyridine |
title_sort | 2,6-bis(2-methyl-1,3-diazinan-2-yl)pyridine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050144/ https://www.ncbi.nlm.nih.gov/pubmed/21522750 http://dx.doi.org/10.1107/S1600536810050063 |
work_keys_str_mv | AT tonquoccuong 26bis2methyl13diazinan2ylpyridine AT boltemichael 26bis2methyl13diazinan2ylpyridine |