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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) 3.5-hydrate
In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water molecules in a distorted octahedral environment. The crystal structures features a three-dimen...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050148/ https://www.ncbi.nlm.nih.gov/pubmed/21522520 http://dx.doi.org/10.1107/S1600536810052785 |
Sumario: | In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water molecules in a distorted octahedral environment. The crystal structures features a three-dimensional network stabilized by extensive O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water molecules is located on a site with half-occupancy. |
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