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Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) 3.5-hydrate

In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water mol­ecules in a distorted octa­hedral environment. The crystal structures features a three-dimen...

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Detalles Bibliográficos
Autores principales: Li, Shi-Jie, Miao, Dong-Liang, Song, Wen-Dong, Tong, Shao-Wei, An, Jing-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050148/
https://www.ncbi.nlm.nih.gov/pubmed/21522520
http://dx.doi.org/10.1107/S1600536810052785
Descripción
Sumario:In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water mol­ecules in a distorted octa­hedral environment. The crystal structures features a three-dimensional network stabilized by extensive O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water mol­ecules is located on a site with half-occupancy.