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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) 3.5-hydrate
In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water molecules in a distorted octahedral environment. The crystal structures features a three-dimen...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050148/ https://www.ncbi.nlm.nih.gov/pubmed/21522520 http://dx.doi.org/10.1107/S1600536810052785 |
| _version_ | 1782199295806537728 |
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| author | Li, Shi-Jie Miao, Dong-Liang Song, Wen-Dong Tong, Shao-Wei An, Jing-Bo |
| author_facet | Li, Shi-Jie Miao, Dong-Liang Song, Wen-Dong Tong, Shao-Wei An, Jing-Bo |
| author_sort | Li, Shi-Jie |
| collection | PubMed |
| description | In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water molecules in a distorted octahedral environment. The crystal structures features a three-dimensional network stabilized by extensive O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water molecules is located on a site with half-occupancy. |
| format | Text |
| id | pubmed-3050148 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30501482011-04-26 Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) 3.5-hydrate Li, Shi-Jie Miao, Dong-Liang Song, Wen-Dong Tong, Shao-Wei An, Jing-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(−) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water molecules in a distorted octahedral environment. The crystal structures features a three-dimensional network stabilized by extensive O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water molecules is located on a site with half-occupancy. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050148/ /pubmed/21522520 http://dx.doi.org/10.1107/S1600536810052785 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Shi-Jie Miao, Dong-Liang Song, Wen-Dong Tong, Shao-Wei An, Jing-Bo Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) 3.5-hydrate |
| title | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) 3.5-hydrate |
| title_full | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) 3.5-hydrate |
| title_fullStr | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) 3.5-hydrate |
| title_full_unstemmed | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) 3.5-hydrate |
| title_short | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) 3.5-hydrate |
| title_sort | diaquabis(5-carboxy-2-propyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))cobalt(ii) 3.5-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050148/ https://www.ncbi.nlm.nih.gov/pubmed/21522520 http://dx.doi.org/10.1107/S1600536810052785 |
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