Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)

In the title compound, (C(8)H(20)N)[ReBr(2)(C(7)H(9)N)(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over...

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Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050163/
https://www.ncbi.nlm.nih.gov/pubmed/21522556
http://dx.doi.org/10.1107/S1600536810050038
Descripción
Sumario:In the title compound, (C(8)H(20)N)[ReBr(2)(C(7)H(9)N)(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions in a 0.66 (1):0.34 (1) ratio. An array of C—H⋯O, C—H⋯Br and N—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure.

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