Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)

In the title compound, (C(8)H(20)N)[ReBr(2)(C(7)H(9)N)(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over...

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Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050163/
https://www.ncbi.nlm.nih.gov/pubmed/21522556
http://dx.doi.org/10.1107/S1600536810050038
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author Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_facet Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_sort Brink, Alice
collection PubMed
description In the title compound, (C(8)H(20)N)[ReBr(2)(C(7)H(9)N)(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions in a 0.66 (1):0.34 (1) ratio. An array of C—H⋯O, C—H⋯Br and N—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure.
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spelling pubmed-30501632011-04-26 Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I) Brink, Alice Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(20)N)[ReBr(2)(C(7)H(9)N)(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions in a 0.66 (1):0.34 (1) ratio. An array of C—H⋯O, C—H⋯Br and N—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050163/ /pubmed/21522556 http://dx.doi.org/10.1107/S1600536810050038 Text en © Brink et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title_full Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title_fullStr Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title_full_unstemmed Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title_short Tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(I)
title_sort tetra­ethyl­ammonium dibromido­tricarbon­yl(o-toluidine)rhenate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050163/
https://www.ncbi.nlm.nih.gov/pubmed/21522556
http://dx.doi.org/10.1107/S1600536810050038
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AT visserhendrikg tetraethylammoniumdibromidotricarbonylotoluidinerhenatei
AT roodtandreas tetraethylammoniumdibromidotricarbonylotoluidinerhenatei

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