Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]

The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta­gonal-bipyramidal geometry, defined by two N atoms from one 2,2′-b...

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Detalles Bibliográficos
Autores principales: Zha, Mei-Qin, Li, Xing, Bing, Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050170/
https://www.ncbi.nlm.nih.gov/pubmed/21522597
http://dx.doi.org/10.1107/S1600536810049640
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author Zha, Mei-Qin
Li, Xing
Bing, Yue
author_facet Zha, Mei-Qin
Li, Xing
Bing, Yue
author_sort Zha, Mei-Qin
collection PubMed
description The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta­gonal-bipyramidal geometry, defined by two N atoms from one 2,2′-bipyridine ligand and five O atoms from three 2-phenyl­quinoline-4-carboxyl­ate ligands, one monodentate, two bidentate. Weak inter­molecular π–π inter­actions [centroid–centroid distance = 3.712 (3) Å] help to establish the packing of the structure.
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spelling pubmed-30501702011-04-26 Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)] Zha, Mei-Qin Li, Xing Bing, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta­gonal-bipyramidal geometry, defined by two N atoms from one 2,2′-bipyridine ligand and five O atoms from three 2-phenyl­quinoline-4-carboxyl­ate ligands, one monodentate, two bidentate. Weak inter­molecular π–π inter­actions [centroid–centroid distance = 3.712 (3) Å] help to establish the packing of the structure. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050170/ /pubmed/21522597 http://dx.doi.org/10.1107/S1600536810049640 Text en © Zha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zha, Mei-Qin
Li, Xing
Bing, Yue
Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title_full Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title_fullStr Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title_full_unstemmed Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title_short Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(2,2′-bipyridine-κ(2) N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) O,O′)cadmium(II)]
title_sort bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ(3) o,o′:o;κ(3) o:o,o′-bis­[(2,2′-bipyridine-κ(2) n,n′)(2-phenyl­quinoline-4-carboxyl­ato-κ(2) o,o′)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050170/
https://www.ncbi.nlm.nih.gov/pubmed/21522597
http://dx.doi.org/10.1107/S1600536810049640
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