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Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)

The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol­ecule and one O atom of a water mol­ecule. The...

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Detalles Bibliográficos
Autores principales: Liu, Ji-Zhong, Zhang, Zhong, Shi, Zhan-Wang, Gao, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050171/
https://www.ncbi.nlm.nih.gov/pubmed/21522554
http://dx.doi.org/10.1107/S1600536810049639
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author Liu, Ji-Zhong
Zhang, Zhong
Shi, Zhan-Wang
Gao, Peng
author_facet Liu, Ji-Zhong
Zhang, Zhong
Shi, Zhan-Wang
Gao, Peng
author_sort Liu, Ji-Zhong
collection PubMed
description The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol­ecule and one O atom of a water mol­ecule. The axial positions are occupied by a carboxyl­ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water mol­ecule forms an intra­molecular O—H⋯O hydrogen bond; an inter­molecular O—H⋯O hydrogen bond gives rise to a dimer.
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spelling pubmed-30501712011-04-26 Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II) Liu, Ji-Zhong Zhang, Zhong Shi, Zhan-Wang Gao, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol­ecule and one O atom of a water mol­ecule. The axial positions are occupied by a carboxyl­ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water mol­ecule forms an intra­molecular O—H⋯O hydrogen bond; an inter­molecular O—H⋯O hydrogen bond gives rise to a dimer. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050171/ /pubmed/21522554 http://dx.doi.org/10.1107/S1600536810049639 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ji-Zhong
Zhang, Zhong
Shi, Zhan-Wang
Gao, Peng
Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_fullStr Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full_unstemmed Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_short Aqua­bis­(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_sort aqua­bis­(benzoato-κo)(1,10-phenanthroline-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050171/
https://www.ncbi.nlm.nih.gov/pubmed/21522554
http://dx.doi.org/10.1107/S1600536810049639
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