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Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050171/ https://www.ncbi.nlm.nih.gov/pubmed/21522554 http://dx.doi.org/10.1107/S1600536810049639 |
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author | Liu, Ji-Zhong Zhang, Zhong Shi, Zhan-Wang Gao, Peng |
author_facet | Liu, Ji-Zhong Zhang, Zhong Shi, Zhan-Wang Gao, Peng |
author_sort | Liu, Ji-Zhong |
collection | PubMed |
description | The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water molecule forms an intramolecular O—H⋯O hydrogen bond; an intermolecular O—H⋯O hydrogen bond gives rise to a dimer. |
format | Text |
id | pubmed-3050171 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501712011-04-26 Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II) Liu, Ji-Zhong Zhang, Zhong Shi, Zhan-Wang Gao, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water molecule forms an intramolecular O—H⋯O hydrogen bond; an intermolecular O—H⋯O hydrogen bond gives rise to a dimer. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050171/ /pubmed/21522554 http://dx.doi.org/10.1107/S1600536810049639 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Ji-Zhong Zhang, Zhong Shi, Zhan-Wang Gao, Peng Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II) |
title | Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full | Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_fullStr | Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full_unstemmed | Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_short | Aquabis(benzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_sort | aquabis(benzoato-κo)(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050171/ https://www.ncbi.nlm.nih.gov/pubmed/21522554 http://dx.doi.org/10.1107/S1600536810049639 |
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