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{3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II)
In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O—...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050172/ https://www.ncbi.nlm.nih.gov/pubmed/21522601 http://dx.doi.org/10.1107/S1600536810051779 |
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author | Rowthu, Sankara Rao Shin, Jong Won Seo, Yu Rim Min, Kil Sik |
author_facet | Rowthu, Sankara Rao Shin, Jong Won Seo, Yu Rim Min, Kil Sik |
author_sort | Rowthu, Sankara Rao |
collection | PubMed |
description | In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O—H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes. |
format | Text |
id | pubmed-3050172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501722011-04-26 {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) Rowthu, Sankara Rao Shin, Jong Won Seo, Yu Rim Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O—H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050172/ /pubmed/21522601 http://dx.doi.org/10.1107/S1600536810051779 Text en © Rowthu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rowthu, Sankara Rao Shin, Jong Won Seo, Yu Rim Min, Kil Sik {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title | {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title_full | {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title_fullStr | {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title_full_unstemmed | {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title_short | {3-[Bis(2-pyridylmethyl-κN)amino-κN]propanol}bis(nitrato-κO)copper(II) |
title_sort | {3-[bis(2-pyridylmethyl-κn)amino-κn]propanol}bis(nitrato-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050172/ https://www.ncbi.nlm.nih.gov/pubmed/21522601 http://dx.doi.org/10.1107/S1600536810051779 |
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