N-(2,4,6-Trimethyl­phen­yl)formamide

The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)–N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol­ecules ar...

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Detalles Bibliográficos
Autores principales: Landman, Marilé, van der Westhuizen, Belinda, Bezuidenhout, Daniela I., Liles, David C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050174/
https://www.ncbi.nlm.nih.gov/pubmed/21522631
http://dx.doi.org/10.1107/S1600536810051469
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author Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_facet Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_sort Landman, Marilé
collection PubMed
description The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)–N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, forming infinite chains along the c axis.
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spelling pubmed-30501742011-04-26 N-(2,4,6-Trimethyl­phen­yl)formamide Landman, Marilé van der Westhuizen, Belinda Bezuidenhout, Daniela I. Liles, David C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)–N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, forming infinite chains along the c axis. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050174/ /pubmed/21522631 http://dx.doi.org/10.1107/S1600536810051469 Text en © Landman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Landman, Marilé
van der Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
N-(2,4,6-Trimethyl­phen­yl)formamide
title N-(2,4,6-Trimethyl­phen­yl)formamide
title_full N-(2,4,6-Trimethyl­phen­yl)formamide
title_fullStr N-(2,4,6-Trimethyl­phen­yl)formamide
title_full_unstemmed N-(2,4,6-Trimethyl­phen­yl)formamide
title_short N-(2,4,6-Trimethyl­phen­yl)formamide
title_sort n-(2,4,6-trimethyl­phen­yl)formamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050174/
https://www.ncbi.nlm.nih.gov/pubmed/21522631
http://dx.doi.org/10.1107/S1600536810051469
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AT vanderwesthuizenbelinda n246trimethylphenylformamide
AT bezuidenhoutdanielai n246trimethylphenylformamide
AT lilesdavidc n246trimethylphenylformamide

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