{1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate

The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol­ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structu...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050176/
https://www.ncbi.nlm.nih.gov/pubmed/21522539
http://dx.doi.org/10.1107/S1600536810053183
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author Kargar, Hadi
Kia, Reza
author_facet Kargar, Hadi
Kia, Reza
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol­ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structure is stabilized by inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and inter­molecular π–π inter­actions with centroid–centroid distances in the range 3.485 (2)–3.845 (3) Å.
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spelling pubmed-30501762011-04-26 {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate Kargar, Hadi Kia, Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol­ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structure is stabilized by inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and inter­molecular π–π inter­actions with centroid–centroid distances in the range 3.485 (2)–3.845 (3) Å. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050176/ /pubmed/21522539 http://dx.doi.org/10.1107/S1600536810053183 Text en © Kargar and Kia 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
{1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title_full {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title_fullStr {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title_full_unstemmed {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title_short {1,1′-[Butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(II) ethanol monosolvate
title_sort {1,1′-[butane-1,4-diylbis(nitrilo­methyl­idyne)]di-2-naphtho­lato}copper(ii) ethanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050176/
https://www.ncbi.nlm.nih.gov/pubmed/21522539
http://dx.doi.org/10.1107/S1600536810053183
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