tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate

In the title compound, C(18)H(22)ClNO(3), the dihedral angle between the benzene ring and the conjugated part of the enaminone ring is 55.19 (9)°. The ester substituent makes a dihedral angle of 81.0 (2)° with this latter moiety. The crystal structure features N—H⋯O and weak C—H⋯O inter­molecular in...

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Detalles Bibliográficos
Autores principales: Alexander, Mariano S., North, Henry, Scott, Kenneth R., Butcher, Ray J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050184/
https://www.ncbi.nlm.nih.gov/pubmed/21522723
http://dx.doi.org/10.1107/S1600536810051743
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author Alexander, Mariano S.
North, Henry
Scott, Kenneth R.
Butcher, Ray J.
author_facet Alexander, Mariano S.
North, Henry
Scott, Kenneth R.
Butcher, Ray J.
author_sort Alexander, Mariano S.
collection PubMed
description In the title compound, C(18)H(22)ClNO(3), the dihedral angle between the benzene ring and the conjugated part of the enaminone ring is 55.19 (9)°. The ester substituent makes a dihedral angle of 81.0 (2)° with this latter moiety. The crystal structure features N—H⋯O and weak C—H⋯O inter­molecular inter­actions.
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spelling pubmed-30501842011-04-26 tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate Alexander, Mariano S. North, Henry Scott, Kenneth R. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(22)ClNO(3), the dihedral angle between the benzene ring and the conjugated part of the enaminone ring is 55.19 (9)°. The ester substituent makes a dihedral angle of 81.0 (2)° with this latter moiety. The crystal structure features N—H⋯O and weak C—H⋯O inter­molecular inter­actions. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050184/ /pubmed/21522723 http://dx.doi.org/10.1107/S1600536810051743 Text en © Alexander et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Alexander, Mariano S.
North, Henry
Scott, Kenneth R.
Butcher, Ray J.
tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title_full tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title_fullStr tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title_full_unstemmed tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title_short tert-Butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
title_sort tert-butyl 4-(4-chloro­anilino)-6-methyl-2-oxocyclo­hex-3-ene­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050184/
https://www.ncbi.nlm.nih.gov/pubmed/21522723
http://dx.doi.org/10.1107/S1600536810051743
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