Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)

In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio­semicarbazone ligand via its thia­zoline N, azomethine N and thiol­ate S atoms. Short inter­molecular N—H⋯Cl and C—H⋯S contacts are prese...

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Detalles Bibliográficos
Autores principales: Viñuelas-Zahínos, Emilio, Luna-Giles, Francisco, Torres-García, Pablo, Bernalte-García, Álvaro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050191/
https://www.ncbi.nlm.nih.gov/pubmed/21522596
http://dx.doi.org/10.1107/S1600536810051500
Descripción
Sumario:In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio­semicarbazone ligand via its thia­zoline N, azomethine N and thiol­ate S atoms. Short inter­molecular N—H⋯Cl and C—H⋯S contacts are present in the crystal structure.

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