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Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2) N (1),S]nickel(II)
In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thiosemicarbazone ligand via its thiazoline N, azomethine N and thiolate S atoms. Short intermolecular N—H⋯Cl and C—H⋯S contacts are prese...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050191/ https://www.ncbi.nlm.nih.gov/pubmed/21522596 http://dx.doi.org/10.1107/S1600536810051500 |
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author | Viñuelas-Zahínos, Emilio Luna-Giles, Francisco Torres-García, Pablo Bernalte-García, Álvaro |
author_facet | Viñuelas-Zahínos, Emilio Luna-Giles, Francisco Torres-García, Pablo Bernalte-García, Álvaro |
author_sort | Viñuelas-Zahínos, Emilio |
collection | PubMed |
description | In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thiosemicarbazone ligand via its thiazoline N, azomethine N and thiolate S atoms. Short intermolecular N—H⋯Cl and C—H⋯S contacts are present in the crystal structure. |
format | Text |
id | pubmed-3050191 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501912011-04-26 Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2) N (1),S]nickel(II) Viñuelas-Zahínos, Emilio Luna-Giles, Francisco Torres-García, Pablo Bernalte-García, Álvaro Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thiosemicarbazone ligand via its thiazoline N, azomethine N and thiolate S atoms. Short intermolecular N—H⋯Cl and C—H⋯S contacts are present in the crystal structure. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050191/ /pubmed/21522596 http://dx.doi.org/10.1107/S1600536810051500 Text en © Viñuelas-Zahínos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Viñuelas-Zahínos, Emilio Luna-Giles, Francisco Torres-García, Pablo Bernalte-García, Álvaro Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2) N (1),S]nickel(II) |
title | Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2)
N
(1),S]nickel(II) |
title_full | Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2)
N
(1),S]nickel(II) |
title_fullStr | Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2)
N
(1),S]nickel(II) |
title_full_unstemmed | Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2)
N
(1),S]nickel(II) |
title_short | Chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κN)ethanone thiosemicarbazonato-κ(2)
N
(1),S]nickel(II) |
title_sort | chlorido[1-(4,5-dihydro-1,3-thiazol-2-yl-κn)ethanone thiosemicarbazonato-κ(2)
n
(1),s]nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050191/ https://www.ncbi.nlm.nih.gov/pubmed/21522596 http://dx.doi.org/10.1107/S1600536810051500 |
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