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Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)

In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio­semicarbazone ligand via its thia­zoline N, azomethine N and thiol­ate S atoms. Short inter­molecular N—H⋯Cl and C—H⋯S contacts are prese...

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Detalles Bibliográficos
Autores principales: Viñuelas-Zahínos, Emilio, Luna-Giles, Francisco, Torres-García, Pablo, Bernalte-García, Álvaro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050191/
https://www.ncbi.nlm.nih.gov/pubmed/21522596
http://dx.doi.org/10.1107/S1600536810051500
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author Viñuelas-Zahínos, Emilio
Luna-Giles, Francisco
Torres-García, Pablo
Bernalte-García, Álvaro
author_facet Viñuelas-Zahínos, Emilio
Luna-Giles, Francisco
Torres-García, Pablo
Bernalte-García, Álvaro
author_sort Viñuelas-Zahínos, Emilio
collection PubMed
description In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio­semicarbazone ligand via its thia­zoline N, azomethine N and thiol­ate S atoms. Short inter­molecular N—H⋯Cl and C—H⋯S contacts are present in the crystal structure.
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spelling pubmed-30501912011-04-26 Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II) Viñuelas-Zahínos, Emilio Luna-Giles, Francisco Torres-García, Pablo Bernalte-García, Álvaro Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio­semicarbazone ligand via its thia­zoline N, azomethine N and thiol­ate S atoms. Short inter­molecular N—H⋯Cl and C—H⋯S contacts are present in the crystal structure. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050191/ /pubmed/21522596 http://dx.doi.org/10.1107/S1600536810051500 Text en © Viñuelas-Zahínos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Viñuelas-Zahínos, Emilio
Luna-Giles, Francisco
Torres-García, Pablo
Bernalte-García, Álvaro
Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title_full Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title_fullStr Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title_full_unstemmed Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title_short Chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κN)ethanone thio­semicarbazonato-κ(2) N (1),S]nickel(II)
title_sort chlorido[1-(4,5-dihydro-1,3-thia­zol-2-yl-κn)ethanone thio­semicarbazonato-κ(2) n (1),s]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050191/
https://www.ncbi.nlm.nih.gov/pubmed/21522596
http://dx.doi.org/10.1107/S1600536810051500
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