Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate

In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligands (tppz). Two thio­cyanate anions act as counter-ions and two water mol­ecules act as solvation agents. O—H⋯N hydr...

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Detalles Bibliográficos
Autores principales: De la Pinta, Noelia, Fidalgo, M. Luz, Ezpeleta, José M., Cortés, Roberto, Madariaga, Gotzon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050193/
https://www.ncbi.nlm.nih.gov/pubmed/21522540
http://dx.doi.org/10.1107/S1600536810053419
Descripción
Sumario:In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligands (tppz). Two thio­cyanate anions act as counter-ions and two water mol­ecules act as solvation agents. O—H⋯N hydrogen bonds are observed in the crystral structure.

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