Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate

In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligands (tppz). Two thio­cyanate anions act as counter-ions and two water mol­ecules act as solvation agents. O—H⋯N hydr...

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Detalles Bibliográficos
Autores principales: De la Pinta, Noelia, Fidalgo, M. Luz, Ezpeleta, José M., Cortés, Roberto, Madariaga, Gotzon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050193/
https://www.ncbi.nlm.nih.gov/pubmed/21522540
http://dx.doi.org/10.1107/S1600536810053419
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author De la Pinta, Noelia
Fidalgo, M. Luz
Ezpeleta, José M.
Cortés, Roberto
Madariaga, Gotzon
author_facet De la Pinta, Noelia
Fidalgo, M. Luz
Ezpeleta, José M.
Cortés, Roberto
Madariaga, Gotzon
author_sort De la Pinta, Noelia
collection PubMed
description In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligands (tppz). Two thio­cyanate anions act as counter-ions and two water mol­ecules act as solvation agents. O—H⋯N hydrogen bonds are observed in the crystral structure.
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spelling pubmed-30501932011-04-26 Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate De la Pinta, Noelia Fidalgo, M. Luz Ezpeleta, José M. Cortés, Roberto Madariaga, Gotzon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligands (tppz). Two thio­cyanate anions act as counter-ions and two water mol­ecules act as solvation agents. O—H⋯N hydrogen bonds are observed in the crystral structure. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050193/ /pubmed/21522540 http://dx.doi.org/10.1107/S1600536810053419 Text en © De la Pinta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
De la Pinta, Noelia
Fidalgo, M. Luz
Ezpeleta, José M.
Cortés, Roberto
Madariaga, Gotzon
Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title_full Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title_fullStr Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title_full_unstemmed Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title_short Bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))nickel(II) dithio­cyanate dihydrate
title_sort bis(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) n (2),n (1),n (6))nickel(ii) dithio­cyanate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050193/
https://www.ncbi.nlm.nih.gov/pubmed/21522540
http://dx.doi.org/10.1107/S1600536810053419
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