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Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate)
In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexafluorophosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050194/ https://www.ncbi.nlm.nih.gov/pubmed/21522610 http://dx.doi.org/10.1107/S1600536810051925 |
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author | Haque, Rosenani A. Salman, Abbas Washeel Whai, Choong Kah Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Haque, Rosenani A. Salman, Abbas Washeel Whai, Choong Kah Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Haque, Rosenani A. |
collection | PubMed |
description | In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexafluorophosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two imidazolium rings are orientated at a dihedral angle of 8.14 (14)°. In the 1-benzyl-3-methylimidazolium units, the dihedral angles between imidazolium and phenyl rings are 80.47 (15) and 76.53 (14)°. The F atoms of the general-position hexafluorophosphate anion are disordered over two sets of sites in a 0.767 (17):0.233 (17) ratio. In the crystal, the hexafluorophosphate anions link the cations into three-dimensional networks via intermolecular C—H⋯F hydrogen bonds and are further consolidated by π–π stacking [centroid–centroid distances = 3.5518 (15) Å] interactions. |
format | Text |
id | pubmed-3050194 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30501942011-04-26 Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) Haque, Rosenani A. Salman, Abbas Washeel Whai, Choong Kah Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexafluorophosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two imidazolium rings are orientated at a dihedral angle of 8.14 (14)°. In the 1-benzyl-3-methylimidazolium units, the dihedral angles between imidazolium and phenyl rings are 80.47 (15) and 76.53 (14)°. The F atoms of the general-position hexafluorophosphate anion are disordered over two sets of sites in a 0.767 (17):0.233 (17) ratio. In the crystal, the hexafluorophosphate anions link the cations into three-dimensional networks via intermolecular C—H⋯F hydrogen bonds and are further consolidated by π–π stacking [centroid–centroid distances = 3.5518 (15) Å] interactions. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050194/ /pubmed/21522610 http://dx.doi.org/10.1107/S1600536810051925 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Haque, Rosenani A. Salman, Abbas Washeel Whai, Choong Kah Quah, Ching Kheng Fun, Hoong-Kun Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title | Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title_full | Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title_fullStr | Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title_full_unstemmed | Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title_short | Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate) |
title_sort | potassium bis[bis(1-benzyl-3-methylimidazolium)silver(i)] tris(hexafluoridophosphate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050194/ https://www.ncbi.nlm.nih.gov/pubmed/21522610 http://dx.doi.org/10.1107/S1600536810051925 |
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