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Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)

In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexa­fluoro­phosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two...

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Autores principales: Haque, Rosenani A., Salman, Abbas Washeel, Whai, Choong Kah, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050194/
https://www.ncbi.nlm.nih.gov/pubmed/21522610
http://dx.doi.org/10.1107/S1600536810051925
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author Haque, Rosenani A.
Salman, Abbas Washeel
Whai, Choong Kah
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Salman, Abbas Washeel
Whai, Choong Kah
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexa­fluoro­phosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two imidazolium rings are orientated at a dihedral angle of 8.14 (14)°. In the 1-benzyl-3-methyl­imidazolium units, the dihedral angles between imidazolium and phenyl rings are 80.47 (15) and 76.53 (14)°. The F atoms of the general-position hexa­fluoro­phosphate anion are disordered over two sets of sites in a 0.767 (17):0.233 (17) ratio. In the crystal, the hexa­fluoro­phosphate anions link the cations into three-dimensional networks via inter­molecular C—H⋯F hydrogen bonds and are further consolidated by π–π stacking [centroid–centroid distances = 3.5518 (15) Å] inter­actions.
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spelling pubmed-30501942011-04-26 Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate) Haque, Rosenani A. Salman, Abbas Washeel Whai, Choong Kah Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K[Ag(C(11)H(12)N(2))(2)](2)(PF(6))(3), the 12-coordinate potassium cation lies on a crystallographic twofold axis and one of the hexa­fluoro­phosphate anions is generated by [Image: see text] symmetry. In the complex cation, the Ag(I) ion is coordinated by two C atoms; the two imidazolium rings are orientated at a dihedral angle of 8.14 (14)°. In the 1-benzyl-3-methyl­imidazolium units, the dihedral angles between imidazolium and phenyl rings are 80.47 (15) and 76.53 (14)°. The F atoms of the general-position hexa­fluoro­phosphate anion are disordered over two sets of sites in a 0.767 (17):0.233 (17) ratio. In the crystal, the hexa­fluoro­phosphate anions link the cations into three-dimensional networks via inter­molecular C—H⋯F hydrogen bonds and are further consolidated by π–π stacking [centroid–centroid distances = 3.5518 (15) Å] inter­actions. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050194/ /pubmed/21522610 http://dx.doi.org/10.1107/S1600536810051925 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Haque, Rosenani A.
Salman, Abbas Washeel
Whai, Choong Kah
Quah, Ching Kheng
Fun, Hoong-Kun
Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title_full Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title_fullStr Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title_full_unstemmed Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title_short Potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(I)] tris­(hexa­fluoridophosphate)
title_sort potassium bis­[bis­(1-benzyl-3-methyl­imidazolium)silver(i)] tris­(hexa­fluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050194/
https://www.ncbi.nlm.nih.gov/pubmed/21522610
http://dx.doi.org/10.1107/S1600536810051925
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