2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol

The title compound, C(15)H(12)F(3)NO(3), is a Schiff base which adopts the cis-quinoid form in the solid state. The dihedral angle between the least-squares planes of the benzene rings being 3.6 (1)°. The F atoms of the –CF(3) group are disordered over two sets of sites with refined occupancies of 0...

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Detalles Bibliográficos
Autores principales: Karadağ, Aslı Tosyalı, Atalay, Şehriman, Genç, Hasan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050197/
https://www.ncbi.nlm.nih.gov/pubmed/21522804
http://dx.doi.org/10.1107/S1600536810050579
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author Karadağ, Aslı Tosyalı
Atalay, Şehriman
Genç, Hasan
author_facet Karadağ, Aslı Tosyalı
Atalay, Şehriman
Genç, Hasan
author_sort Karadağ, Aslı Tosyalı
collection PubMed
description The title compound, C(15)H(12)F(3)NO(3), is a Schiff base which adopts the cis-quinoid form in the solid state. The dihedral angle between the least-squares planes of the benzene rings being 3.6 (1)°. The F atoms of the –CF(3) group are disordered over two sets of sites with refined occupancies of 0.61 (5) and 0.39 (5). An intra­molecular N—H⋯O hydrogen bond occurs. The crystal structure is stabilized by inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-30501972011-04-26 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol Karadağ, Aslı Tosyalı Atalay, Şehriman Genç, Hasan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)F(3)NO(3), is a Schiff base which adopts the cis-quinoid form in the solid state. The dihedral angle between the least-squares planes of the benzene rings being 3.6 (1)°. The F atoms of the –CF(3) group are disordered over two sets of sites with refined occupancies of 0.61 (5) and 0.39 (5). An intra­molecular N—H⋯O hydrogen bond occurs. The crystal structure is stabilized by inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050197/ /pubmed/21522804 http://dx.doi.org/10.1107/S1600536810050579 Text en © Karadağ et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karadağ, Aslı Tosyalı
Atalay, Şehriman
Genç, Hasan
2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title_full 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title_fullStr 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title_full_unstemmed 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title_short 2-[(E)-2-Hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
title_sort 2-[(e)-2-hy­droxy-5-(trifluoro­meth­oxy)benzyl­idene­amino]-4-methyl­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050197/
https://www.ncbi.nlm.nih.gov/pubmed/21522804
http://dx.doi.org/10.1107/S1600536810050579
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