Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate

The title compound, C(14)H(15)NO(5), was obtained from the reaction of acetanilide with dimethyl acetyl­enedicarboxyl­ate in the presence of potassium carbonate. The C=C double bond adopts an E configuration and the geometry around the amide N atom is almost planar rather than pyramidal (mean deviat...

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Detalles Bibliográficos
Autores principales: Guo, Shui Liang, Fu, Chen, Wen, Ting Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050198/
https://www.ncbi.nlm.nih.gov/pubmed/21522789
http://dx.doi.org/10.1107/S1600536810050890
Descripción
Sumario:The title compound, C(14)H(15)NO(5), was obtained from the reaction of acetanilide with dimethyl acetyl­enedicarboxyl­ate in the presence of potassium carbonate. The C=C double bond adopts an E configuration and the geometry around the amide N atom is almost planar rather than pyramidal (mean deviation of 0.0032 Å from the C(3)N plane). The packing of the mol­ecules in the crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds.

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