Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate

The title compound, C(14)H(15)NO(5), was obtained from the reaction of acetanilide with dimethyl acetyl­enedicarboxyl­ate in the presence of potassium carbonate. The C=C double bond adopts an E configuration and the geometry around the amide N atom is almost planar rather than pyramidal (mean deviat...

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Detalles Bibliográficos
Autores principales: Guo, Shui Liang, Fu, Chen, Wen, Ting Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050198/
https://www.ncbi.nlm.nih.gov/pubmed/21522789
http://dx.doi.org/10.1107/S1600536810050890
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author Guo, Shui Liang
Fu, Chen
Wen, Ting Bin
author_facet Guo, Shui Liang
Fu, Chen
Wen, Ting Bin
author_sort Guo, Shui Liang
collection PubMed
description The title compound, C(14)H(15)NO(5), was obtained from the reaction of acetanilide with dimethyl acetyl­enedicarboxyl­ate in the presence of potassium carbonate. The C=C double bond adopts an E configuration and the geometry around the amide N atom is almost planar rather than pyramidal (mean deviation of 0.0032 Å from the C(3)N plane). The packing of the mol­ecules in the crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30501982011-04-26 Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate Guo, Shui Liang Fu, Chen Wen, Ting Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(15)NO(5), was obtained from the reaction of acetanilide with dimethyl acetyl­enedicarboxyl­ate in the presence of potassium carbonate. The C=C double bond adopts an E configuration and the geometry around the amide N atom is almost planar rather than pyramidal (mean deviation of 0.0032 Å from the C(3)N plane). The packing of the mol­ecules in the crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050198/ /pubmed/21522789 http://dx.doi.org/10.1107/S1600536810050890 Text en © Guo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guo, Shui Liang
Fu, Chen
Wen, Ting Bin
Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title_full Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title_fullStr Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title_full_unstemmed Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title_short Dimethyl (E)-2-(N-phenyl­acetamido)­but-2-enedioate
title_sort dimethyl (e)-2-(n-phenyl­acetamido)­but-2-enedioate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050198/
https://www.ncbi.nlm.nih.gov/pubmed/21522789
http://dx.doi.org/10.1107/S1600536810050890
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AT fuchen dimethyle2nphenylacetamidobut2enedioate
AT wentingbin dimethyle2nphenylacetamidobut2enedioate

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